Azide groups in high oxidation state Mn carboxylate chemistry: a new Mn(11) complex and its conversion to a Mn(25) azide complex with Me(3)SiN(3).
نویسندگان
چکیده
A new high oxidation state Mn(III/IV)(11) carboxylate complex has been prepared and then converted to a Mn(II/III)(25) azide/carboxylate cluster with Me(3)SiN(3); the Mn(25) product is the initial example of a higher oxidation state Mn azide complex not stabilized by any chelate ligands.
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ورودعنوان ژورنال:
- Chemical communications
دوره 20 شماره
صفحات -
تاریخ انتشار 2009